EC-MS Resources

SEE SOME OF THE MAIN APPLICATIONS OF THE EC-MS BELOW

user manual

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videos

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Application and technical notes

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Publications

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Whitepaper

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Data analysis code

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Software Downloads

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Videos - Spectro Inlets

Application & technical notes

tech1

Technical note #1 

Gas Pulses 

Technical note #2 

Benchmark Measurement 

Technical note #3 

Potentiostat instability 

Technical note #4

Non-aqueous 

Technical note #5

Tuning of the QMS 

glovebox

Technical note #6 

Air-free transfer from glovebox 

Technical note #7 

Soft ionization 

tech9

Technical note #9 

Setting up ion gauge interlock 

Technical note #11 

Avoiding MS-Signal fluctuations caused by bubbles 

Technical note #16 

Best Practices for OER experiments 

Technical note #17 

Best practices using EC‐MS system for HER 

Application note #1 

CO-stripping 

Application note #2 

EC‐MS Quantification using ixdat

Application note #3 

Hydrogen evolution reaction using
EC‐MS system

Application note #4 

Oxygen evolution reaction using
EC‐MS system

Data analysis code

We recommend the Spectro Inlets co-developed open-source package ixdat for data analysis. The ixdat package features easy data access and power plotting and analysis tools for combined techniques, such as ECMS. ixdat will get you up to speed on your ECMS data treatment in no time. The documentation for the package can be found here: https://ixdat.readthedocs.io/en/latest/

Below is an example of how we use the package for the treatment of EC-MS data to generate the figures in our application notes:

Publications

Raciti, D., & Moffat, T. P. (2022). Quantification of Hydride Coverage on Cu(111) by Electrochemical Mass Spectrometry. The Journal of Physical Chemistry C. https://doi.org/10.1021/acs.jpcc.2c06207 

Silvioli, L., Winiwarter, A., Scott, S., Castelli, I., Moses, P., Chorkendorff, I., Seger, B., & Rossmeisl, J. (2022). Rational Catalyst Design for Higher Propene Partial Electro-oxidation Activity by Alloying Pd with Au. The Journal of Physical Chemistry C, 126. https://doi.org/10.1021/acs.jpcc.1c10095

Krzywda, P. M., Paradelo Rodríguez, A., Benes, N. E., Mei, B. T., & Mul, G. (2022). Carbon-Nitrogen bond formation on Cu electrodes during CO2 reduction in NO3- solution. Applied Catalysis B: Environmental, 121512. https://doi.org/10.1016/j.apcatb.2022.121512

Oates, R. P., Murawski, J., Hor C., Shen, X., Weber, D. J., Oezaslan, M., Shaffer, M. S. P., & Stephens, I. E. L. (2022). How to Minimise Hydrogen Evolution on Carbon Based Materials?. Journal of The Electrochemical Society,169(5), 054516. https://iopscience.iop.org/article/10.1149/1945-7111/ac67f7/meta

Krempl, K., Hochfilzer, D., Cavalca, F., Saccoccio, M., Kibsgaard, J., Vesborg, P., & Chorkendorff, I. (2022). Quantitative Operando Detection of Electro Synthesized Ammonia Using Mass Spectrometry. ChemElectroChem, 9(6), e202101713. https://doi.org/10.1002/celc.202101713

Hochfilzer, Degenhart; Xu, Aoni; Sørensen, Jakob Ejler; Needham, Julius Lucas; Krempl, Kevin; Toudahl, Karl Krøjer; et al. (2022). Transients in Electrochemical CO Reduction Explained by Mass Transport of Buffers. ACS Publications. Collection. https://doi.org/10.1021/acscatal.2c00412

Krzywda, P. M., Paradelo Rodríguez, A., Cino, L., Benes, N. E., Mei, B. T., & Mul, G. (2022). Electroreduction of NO3− on tubular porous Ti electrodes. Catal. Sci. Technol. https://doi.org/10.1039/D2CY00289B 

Scott, S. B., Sørensen, J. E., Rao, R. R., Moon, C., Kibsgaard, J., Shao-Horn, Y., & Chorkendorff, I. (2022). The low overpotential regime of acidic water oxidation part II: trends in metal and oxygen stability numbers. Energy Environ. Sci. https://doi.org/10.1039/D1EE03915F 

Scott, S. B., Rao, R., Moon, C., Sørensen, J. E., Kibsgaard, J., Shao-Horn, Y., & Chorkendorff, I. (2022). The low overpotential regime of acidic water oxidation part I: The importance of O2 detection. Energy Environ. Sci. https://doi.org/10.1039/D1EE03914H 

Tackett, B. M., Raciti, D., Hight Walker, A. R., & Moffat, T. P. (2021). Surface Hydride Formation on Cu(111) and Its Decomposition to Form H2 in Acid Electrolytes. The Journal of Physical Chemistry Letters, 12(44), 10936–10941. https://doi.org/10.1021/acs.jpclett.1c03131

Zheng, Y.-R., Vernieres, J., Wang, Z., Zhang, K., Hochfilzer, D., Krempl, K., Liao, T.-W., Presel, F., Altantzis, T., Fatermans, J., Scott, S. B., Secher, N. M., Moon, C., Liu, P., Bals, S., van Aert, S., Cao, A., Anand, M., Nørskov, J. K., Kibsgaard, J., Chorkendorff, I. (2021). Monitoring oxygen production on mass-selected iridium–tantalum oxide electrocatalysts. Nature Energy. https://doi.org/10.1038/s41560-021-00948-w

Krzywda, P. M., Paradelo Rodriguez, A., Benes, N. E., Mei, B., & Mul, G. (2021). Effect of electrolyte and electrode configuration on Cu‐catalyzed nitric oxide reduction to ammonia. ChemElectroChem. https://doi.org/10.1002/celc.202101273

 
Smiljanić, M., Petek, U., Bele, M., Ruiz-Zepeda, F., Šala, M., Jovanovič, P., Gaberšček, M., & Hodnik, N. (2021). Electrochemical Stability and Degradation Mechanisms of Commercial Carbon-Supported Gold Nanoparticles in Acidic Media. The Journal of Physical Chemistry C, 125(1). https://doi.org/10.1021/acs.jpcc.0c10033
 
Stumm, C., Kastenmeier, M., Waidhas, F., Bertram, M., Sandbeck, D. J. S., Bochmann, S., Mayrhofer, K. J. J., Bachmann, J., Cherevko, S., Brummel, O., & Libuda, J. (2021). Model electrocatalysts for the oxidation of rechargeable electrofuels – carbon supported Pt nanoparticles prepared in UHV. Electrochimica Acta, 389. https://doi.org/10.1016/j.electacta.2021.138716
 
 
Tanumihardja, E., Paradelo Rodríguez, A., Loessberg-Zahl, J. T., Mei, B., Olthuis, W., & van den Berg, A. (2021). On-chip electrocatalytic NO sensing using ruthenium oxide nanorods. Sensors and Actuators B: Chemical, 334. https://doi.org/10.1016/j.snb.2021.129631
 
Moriau, L., Koderman Podboršek, G., Surca, A. K., Semsari Parpari, S., Šala, M., Petek, U., Bele, M., Jovanovič, P., Genorio, B., & Hodnik, N. (2021). Enhancing Iridium Nanoparticles’ Oxygen Evolution Reaction Activity and Stability by Adjusting the Coverage of Titanium Oxynitride Flakes on Reduced Graphene Oxide Nanoribbons’ Support. Advanced Materials Interfaces, 8(17). https://doi.org/10.1002/admi.202100900
 

Hochfilzer, D., Sørensen, J. E., Clark, E. L., Scott, S. B., Chorkendorff, I., & Kibsgaard, J. (2021). The Importance of Potential Control for Accurate Studies of Electrochemical CO Reduction. ACS Energy Letters, 6(5). https://doi.org/10.1021/acsenergylett.1c00496

Krempl, K., Hochfilzer, D., Scott, S. B., Kibsgaard, J., Vesborg, P. C. K., Hansen, O., & Chorkendorff, I. (2021). Dynamic Interfacial Reaction Rates from Electrochemistry–Mass Spectrometry. Analytical Chemistry, 93(18). https://doi.org/10.1021/acs.analchem.1c00110
 
Scott, S. B., Kibsgaard, J., Vesborg, P. C. K., & Chorkendorff, I. (2021). Tracking oxygen atoms in electrochemical CO oxidation – Part II: Lattice oxygen reactivity in oxides of Pt and Ir. Electrochimica Acta, 374. https://doi.org/10.1016/j.electacta.2021.137844
 
Scott, S. B., Kibsgaard, J., Vesborg, P. C. K., & Chorkendorff, I. (2021). Tracking oxygen atoms in electrochemical CO oxidation – Part I: Oxygen exchange via CO2 hydration. Electrochimica Acta, 374, 137842. https://doi.org/10.1016/j.electacta.2021.137842
 
 

Winiwarter, A., Boyd, M. J., Scott, S. B., Higgins, D. C., Seger, B., Chorkendorff, I., & Jaramillo, T. F. (2021). CO as a Probe Molecule to Study Surface Adsorbates during Electrochemical Oxidation of Propene. ChemElectroChem, 8(1). https://doi.org/10.1002/celc.202001162

 
 

Scott, S. B., Engstfeld, A. K., Jusys, Z., Hochfilzer, D., Knøsgaard, N., Trimarco, D. B., Vesborg, P. C. K., Behm, R. J., & Chorkendorff, I. (2020). Anodic molecular hydrogen formation on Ru and Cu electrodes. Catalysis Science & Technology, 10(20). https://doi.org/10.1039/D0CY01213K

Winiwarter, A., Silvioli, L., Scott, S. B., Enemark-Rasmussen, K., Sariç, M., Trimarco, D. B., Vesborg, P. C. K., Moses, P. G., Stephens, I. E. L., Seger, B., Rossmeisl, J., & Chorkendorff, I. (2019). Towards an atomistic understanding of electrocatalytic partial hydrocarbon oxidation: propene on palladium. Energy & Environmental Science, 12(3). https://doi.org/10.1039/C8EE03426E
 
Roy, C., Sebok, B., Scott, S. B., Fiordaliso, E. M., Sørensen, J. E., Bodin, A., Trimarco, D. B., Damsgaard, C. D., Vesborg, P. C. K., Hansen, O., Stephens, I. E. L., Kibsgaard, J., & Chorkendorff, I. (2018). Impact of nanoparticle size and lattice oxygen on water oxidation on NiFeOxHy. Nature Catalysis, 1(11). https://doi.org/10.1038/s41929-018-0162-x
 
Trimarco, D. B., Scott, S. B., Thilsted, A. H., Pan, J. Y., Pedersen, T., Hansen, O., Chorkendorff, I., & Vesborg, P. C. K. (2018). Enabling real-time detection of electrochemical desorption phenomena with sub-monolayer sensitivity. Electrochimica Acta, 268. https://doi.org/10.1016/j.electacta.2018.02.060
D. B. Trimarco, (2017). Real-time detection of sub-monolayer desorption phenomena during electrochemical reactions: Instrument development and applications. PhD thesis, Department of Physics, Technical University of Denmark. https://orbit.dtu.dk/en/publications/real-time-detection-of-sub-monolayer-desorption-phenomena-during-
 
D. B. Trimarco, P. C. K. Vesborg, T. Pedersen, O. Hansen, I. Chorkendorff, (2016), patent,A device for extracting volatile species from a liquid. http://orbit.dtu.dk/en/publications/a-device-for-extracting-volatile-species-from-a-liquid(3e58dfe1-948c-4936-bdda-a0d2afe32b41)/export.html
 
Trimarco, D. B., Pedersen, T., Hansen, O., Chorkendorff, I., & Vesborg, P. C. K. (2015). Fast and sensitive method for detecting volatile species in liquids. Review of Scientific Instruments, 86(7). https://doi.org/10.1063/1.4923453
 
 

Software downloads

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Zilien version 2.4.0

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